Reaction: [glycerol dehydratase]-activating enzyme List of reactions

Reaction name: [glycerol dehydratase]-activating enzyme Reaction type: cognate
EC number: Kegg ID: Rhea ID:
Directionality: reversible Curation status: valid Classification: public
Description:A single glycine residue in EC 4.2.1.30, B12-independent glycerol dehydratase, is oxidized to the corresponding radical by transfer of H from its CH2 to S-adenosyl-L-methionine (AdoMet) with concomitant cleavage of the latter.
Curator notes:The identity of the other species that accepts one of the electrons from the reaction is not clear.
ID Type Compound ID Name Stoichiometry Curator notes
pdb 1r8w glycerol dehydratase (inactive) 1 Specifically, the Gly residue that is to become an activated glycyl radical.
chebi 67040 S-adenosyl-L-methioninate 1
chebi 62787 1,5-dihydroflavin 1
ID Type Compound ID Name Stoichiometry Curator notes
pdb 1r8w glycerol dehydratase (active) 1
chebi 57844 L-methionine zwitterion 1
chebi 17319 5'-deoxyadenosine 1
chebi 15817 semiquinone 1

Reaction

[glycerol dehydratase]-activating enzyme

+ + + + +
glycerol dehydratase (inactive)
1r8w
S-adenosyl-L-methioninate
67040
1,5-dihydroflavin
62787
glycerol dehydratase (active)
1r8w
L-methionine zwitterion
57844
5'-deoxyadenosine
17319
semiquinone
15817

EC: | IntEnz: | Kegg: | BioCyc: | BRENDA: |